Sorbents:
Sorbents reversibly
bind and release chemicals, and can be used either to remove pollutants from
a process or exhaust stream, or to transfer a useful chemical from one environment
to another. TDA develops sorbents that work via physisorption at room temperature,
and high temperature sorbents that chemically react and bind tightly with the
species to be removed or transferred. Many of our high temperature sorbents
can be chemically or thermally cycled to bind and release the target gas millions
of times without degrading. Our areas of expertise include:
- Removal of trace
metals from gasified coal: Regenerable and expendable sorbents that remove
trace metals such as mercury, arsenic from gasified coal at elevated temperatures.
- Removal of H2S
from gasified coal: Zinc and iron based fixed bed, moving bed and fluidized
bed regenerable sorbents that can remove H2S from hot syngas or
coal gasifier streams at elevated temperatures.
- Removal of
Organosulfur: Sorbents that remove odorants from
natural gas and propane, thereby improving the operation of fuel cells, and
sorbents that remove organic sulfur compounds from
liquid
fuels.
- Oxygen Sorbents:
Regenerable chemical sorbents that can pick up and release oxygen at high
temperatures are useful in reforming to make syngas and hydrogen, power generation
(chemical looping combustion) and industrial processes.
- CO2
Sorbents: Regenerable high-temperature sorbents that chemically react with
and release CO2 improve the efficiency and reduce the cost of hydrogen
production, while low temperature sorbents can remove CO2 from
breathing air in a spacesuit.
-
Mercury
Sorbents: Sorbents that remove all species of mercury from the flue
gases of coal-fired power plants, even at elevated temperatures.
- HCl Recovery
and Recycle: Chemical sorbents can recover HCl from chemical waste streams
and for recycle and conversion to more valuable Cl2.
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